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KarlSethMoran t1_jd4ys58 wrote

Reply to comment by RevengencerAlf in Can a single atom be determined to be in any particular phase of matter? by Zalack

Sure. That is the electronic temperature. I was coming from the perspective of a classical point-particle picture and the kinetic, not thermodynamic, definition of temperature.

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MarzipanMission t1_jd520vi wrote

How is thermodynamic temperature different from viewing it from a kinetic perspective?

Does that mean that the movement of atoms relative to each other, in the kinetic sense of temperature, is not what the temperatures talk about in thermodynamics? So temperature is not a universal concept then? It is context dependent, and has many definitions?

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sticklebat t1_jd58ks6 wrote

Thermodynamic temperature is defined as the rate at which the internal energy of a system changes as its entropy changes.

In contrast, temperature from kinetic theory is essentially a measure of the average translational kinetic energy of the particles in a system.

The two are sometimes, but not typically, equal. The temperature that you know and love is the second one, but thermodynamic temperature is also widely used in science.

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wnoise t1_jd5kly2 wrote

The second is special case of the first. The statistical mechanics temperature really is the fundamental one.

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sticklebat t1_jd5ppqo wrote

Yep. But in most scenarios corresponding to human experience the first is reasonably applicable and much easier to understand.

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Dr-Luemmler t1_jd7c3ex wrote

>So temperature is not a universal concept then? It is context dependent, and has many definitions?

Yes it has, but the definitions are all different sides of the same coin. Or in other words, they add in complexity, but are more or less the same. They are not contradicting.

Temperature IS the average kinetic energy of a systems particles. Thats not just the classical definition that is also the result if you combine quantum theory and statistical thermodynamics. This kinetic energy just is not only translational but also rotation and vibration. A single atom though, does not have the degrees of freedom to rotate or vibrate. Besides its spin, but that is not important here.

There is another dof, and thats the electronic one. Yes, here energy can also be stored. Also probably neglectable here, but OP was very unprecise with his thought experiment here...

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