hydroxypcp t1_jc9tak2 wrote
Reply to comment by stefek132 in Radon is a monatomic gas, but its decay products are solids. After a decay, what happens to the individual atoms of the daughter elements? Do they stay suspended in the atmosphere or slowly rain out? by foodtower
I disagree. For one, a single lead atom is basically a radical so there is no energy barrier to overcome on its side for the reaction to occur (since it has no metallic bond to other Pb atoms). This means the likelihood of a reaction with all other collision parameters being the same is increased by orders of magnitude
Second, things move hella fast at room temp and the mean free path length at STP is very small. This means that it will have collided with air molecules a whole lot before it reaches any surface. I don't remember the numbers off the top of my head for some shoddy napkin math but I'm very confident that if we account for both these factors, Pb will have reacted with oxygen with a very high likelihood before touching a surface unless it formed like, right next to it.
honey_102b t1_jca39xa wrote
you are right. it will instantly react with oxygen radicals which are freely available from photo dissociation of O3 and NO2.
JeffieSandBags t1_jcafsvc wrote
How likely to hit those though? Really low, right?
Twink_Ass_Bitch t1_jcbu73r wrote
Isolated metal atoms are actually very reactive compared to metal atoms bound in a bulk solid phase. It wouldn't surprise me if a lead atom would spontaneously react with gases in the atmosphere.
Bbrhuft t1_jcdzt3r wrote
The radon progeny, Bi-214 and Pb-214 do not react with oxygen, except sometimes Po-218.
They start off are singly ionized ions (Po+, Pb+, Bi+). As a result, reactions with Volatile Organic Compounds (VOCs), which commonly contaminates air, especially indoor air, is favoured over oxygen. They also react with hydroxyl radicals, ionized water vapour that's formed in the ionization trail of their recoil path (Po-218 recoils at 13 million mph, after Radon-222 emits an Alpha particle travelling at 7% the speed of light).
These reactions form minute particles, 1.2 to 2 nm in diameter, likely consisting of clusters of 5 to 8 water molecules and a few molecules of VOCs surrounding a now neutral atom of Pb or Bi.
That said, some Po-218 ions react to form Po oxide. This is shown by a double peak in measured particle size distribution of radon Po progeny particles; Po forms a double peak, smaller particles of PoOx of 0.5 - 1.5 nm and much lager particles (c. 15 nm) of a Po atom surrounded by SO2, water and VOC molecules much larger than Bi-214 and Pb-214 clusters.
Castleman Jr, A.W., 1991. Consideration of the chemistry of radon progeny. Environmental science & technology, 25(4), pp.730-735.
Hopke, P., 1996. The initial atmospheric behavior of radon decay products. Journal of Radioanalytical and Nuclear Chemistry, 203(2), pp.353-375.
Bbrhuft t1_jcdxda3 wrote
Po-218, Lead-214 and bismuth-214 are singly ionized ions. Since they are singly ionized, reactions with oxygen are not favoured, they are instead predicted to hydrolyse with hydroxyl radicals and with trace Volatile Organic Compounds (VOCs) that often contaminate air, indoor air in particular.
Also, you must consider the effects of the radiation and kinetic recoil of the ions, their velocity, c. 10-13 million mph for Po-218 ions after they emit an Alpha particles at 7% the speed of light. Lead-214 and Bismuth-214 also form in ionization trails, generated by Beta particles. As a result, chemical reactions, and thus neutralization of the ions, take place with hydroxyl radicals generated from ionized water vapour, and also, likely NO₂.
The reaction products of radon progeny grow and form ultrafine particles, 1.2 to 2 nanometres in diameter, these likely consist of 5 to 8 molecules of water and a few molecules of VOCs. These stick to dust or settle on solid surfaces, i.e. radon progeny plate out.
>The chemical and physical properties of 218Po immediately following its formation from 222Rn decay are important in determining its behavior in indoor atmospheres and play a major part in determining its potential health effects. In 88% of the decays, a singly charged, positive ion of 218Po is obtained at the end of its recoil path. > >These ions can interact with water vapor or other volatile organic compounds (VOCs) that may exist in indoor air. > >The ions can be neutralized by 3 different mechanisms, small-ion recombination, electron transfer, and electron scavenging. In typical indoor air, the ion will be rapidly neutralized by transfer of electrons from lower ionization potential gases such as NO2. > >The neutral molecule can then become incorporated in ultrafine particles formed by the radiolytic processes in the recoil path. These particles will typically be formed by the presence of the air ions produced by the passage of the emitted α-particle through ion-induced nucleation. > >In addition these energetic ions can react with water molecules to produce hydroxyl radicals. > >Thus, the decay of the radon nucleus produces a variety of effects and can result in changes in the size of the radioactive species that includes the radon progeny.
Refs.:
Castleman Jr, A.W., 1991. Consideration of the chemistry of radon progeny. Environmental science & technology, 25(4), pp.730-735.
Hopke, P., 1996. The initial atmospheric behavior of radon decay products. Journal of Radioanalytical and Nuclear Chemistry, 203(2), pp.353-375.
stefek132 t1_jc9yvvf wrote
Well, all you’re saying is right. But it’s also pretty unlikely to really find a single Pb atom flying around. There’d be a gradient originating from the source, with most heavy Pb atoms actually chilling at the source and not wanting to really move (think elastic impact) as all the other atoms/molecules colliding with it have way less mass. Only the most energetic ones escape (we’re overlooking any kinds of wind here for simplicity, just focusing on the thermal energy). So Pb will most likely see other Pb and form more inert clusters before even noticing any other molecules flying around. Those clusters will get oxidised on the surface eventually, but definitely not instantly or „quickly“ (however uncertain that term might be).
Now, in a realistic scenario, with wind working it’s magic and mixing everything, you’re probably right to disagree. That’s why my answer was „yes and no“. Realistically, it’d probably get oxidised at some point. Even a radical reacting with another radical needs to (Pb and O2/O•) fulfil certain strict geometrical conditions in order to pair the lone electrons. Those conditions can only be achieved randomly and under a certain energy threshold, which is why radicals in gas phase can be (but definitely don’t have to) pretty stable. I aimed to explain the reasons why this isn’t really a straightforward case.
Again. So basically, it’s pretty unlikely that a single Pb gets quickly oxidised. It will happen to some atoms though. It’s way more likely for Pb to form bigger clusters, which are more probable to hit (or rather be hit by) oxygen to react on their surface.
Edit: I’m all for napkin math though. I’ll try to remember to do it later.
mali73 t1_jcab1m0 wrote
"Even [diatomic radical reactions] must fulfil strict geometrical (sic) conditions in order to pair lone electrons" I don't agree with. There is genuinely only 1 geometric paramater, i.e. the distance between the two atoms, unless you are implying Born-Oppenheimer doesn't apply or relativistic effects are necessary (which, they are, but for which your bouncing ball model doesn't account). Even the angle between their velocities does not matter following from Newtonian relativity.
I also believe your "energy threshold" (Eyering transition state Gibbs free energy?) is being imagined as far too high. Ground state monoatomic oxygen and lead must overcome only Pauli repulsion in the formation of the transition state, which will be on the same order of magnitude as Coulombic benefit entering the transition state, so I posit ca. 10% of bond enthalpy as the maximum barrier? Which for even the strongest diatomic leaves us with 90 kJ/mol, which for an ordinary reaction proceeds unmonitorably quickly at room temperature, for a more reasonable guess of 20 kJ/mol we need an argon matrix to observe these using IR spectroscopy. Reaction with triplet and heaven forbid singlet dioxygen will likely have larger barriers. Do I think these barriers will be large enough to stop reaction with a radon daughter lead? No not at all. Even under your assumptions.
Saying it will only occur when it forms larger clusters is frankly laughable. The ionisation energy goes up, the Gibbs free enegy of the transition state goes up, and frankly the chance of interacting with oxygen goes down, not up when forming a cluster. The total reactive lead surface area goes down rapidly with cluster size as core atoms become inaccessible, and on forming a cluster the volume goes down from overlapping atomic radii. On small clusters the cluster radius is a similar fraction of the mean free path as the atomic radius of a lead atom is of the mean free path, so forming a Pb(0) tetramer roughly quarters your reaction time. Lead metal sheets oxidises slowly, and can readily be chemically forced back to metal, however fine lead powder can ignite simply by throwing it through air.
Your assumption that lead clusters are forming in preference to reaction with oxygen is only true if your amount of parent radon is decaying much faster than it is diffusing or you have far more radon than oxygen. This is not true, as isolable radon (222Rn) has a half life of almost 4 days. Under any reasonable conditions this is much slower than diffusion and all radon will be well mixed with the surrounding air.
I would be frankly shocked to see any metallic lead deposition at all. I tried to read about experimental evidence for this however daughter isotope measurement is only performed by radiation measurments rather than any chemical means so the identity of the material is never stated (comprehensive article by Yamamoto et al. in J. Environ. Radioactivity).
Bbrhuft t1_jcajnfa wrote
FYI. have a radium dial compass sealed inside an air tight jar, safely stored in an unoccupied room. It's highly radioactive, back then Zinc sulfide phosphor wasn't particularly sensitive so they compensated by adding extra radium.
Anyway, the interior of the jar gets coated with radon daughter plate out:
This is the decay I measured, due to Bismuth-214 and Lead-214 decay.
Anyways, the contamination stubbornly adhers to the glass. I tried rubbing it off with tissues, dampened with water and alcohol. I estimate I can remove about 25% of the contamination, by measuring the radioactivity on the tissue, most remains stuck to the glass.
Radon Plate Out occurs because the decay products (218Po, 214Pb and 214Bi) are electrically charged, they are attracted to dust and surfaces that are slightly charged.
mergelong t1_jcapyht wrote
I find that pretty interesting, but I imagine that especially the upper atmosphere, with high levels of ionizing radiation and radicals floating around, doesn't resemble inside of a jar, not to mention the distance the daughter nuclides must travel before deposition is vastly increased for atmospheric radon decay products.
Bbrhuft t1_jcat9ql wrote
Radon Daughters stick to dust at ground level and that dust is carried into the higher atmosphere by rising air currents, they can rain out when there's heavy rain, thunderstorms particularly, a phenomena called Radon Washout.
It was discovered by accident in the 1960s. A nuclear worker walked though puddles in a car park on the way to work, and he set off the alarms as he arrived, since that's backwards they were intrigued, and they discovered that atmospheric dust is coated with radon daughters which can get concentrated in electrically charged thunderstorms, and rain out as Radon Washout.
Radon Washout can sometimes be intensely radioactive, and there's a paper that estimated that a few percent of skin cancers might be linked to Radon Washout, beta radiation from Lead-214 and Bismuth-214 decay is able to penetrate the outer layers of the skin and deposit a radiation dose to living skin cells, a risk increased for people who work outdoors. This might be speculative, nevertheless, it illustrates just how radioactive rain can be sometimes be when weather conditions are just right.
I measured it myself a few times. Got readings up to 2 microsieverts per hour, nothing spectacular.
Styro, B.I. and Stelingis, K.I., 1978. On the value of flow of long-lived radon-222 decay products into atmosphere with the dust of natural and anthropogenic origin. In Chemical and radioactive pollution of the atmosphere and hydrosphere. V. 4.
Edit: Also, >90% of indoor radon daughters are bound to dust, very little is unbound, free floating.
drsoftware t1_jcb2kj7 wrote
Another writer responded with mean free path and velocity for particles. Given that dust, that is other larger masses than individual oxygen atoms, will the electrically charge particle be much more likely to first bound with oxygen and then with dust?
[deleted] t1_jcb3omc wrote
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Bbrhuft t1_jcfday0 wrote
One important consideration is the fact that Lead-214 and Bismuth-214 are electrically charged, singly ionized ions. The other factor that needs to be taken into account is the fact that these reactions occur within an ionization trail that contains hydroxyl radicals and NO2 (the Alpha particles are ejected at 7-8% the speed of light, and the daughter atoms recoil at 10 to 13 million mph). And the final factor that make all this more complex that single atoms floating in nitrogen and oxygen is the fact that air isn't pure, but is often contaminated with volatile organic compounds, particularly indoor air, and SO2.
As a result Lead and bismuth oxide isn't formed. They form clusters of 5 to 8 water molecules and often a few molecules of VOCs. They were measured experimentally, and are 1.2 - 2 nanometers in diameter.
Po-218 is a little different, it can form larger clusters about 15 nm that additionally contain SO2 (if air contains a few ppm of SO2, common in urban and inner city environments), and water molecules. It can also form much smaller clusters of PoOx, 0.5 - 1 nm.
I think I've summarize what I read correctly.
Ref.:
Castleman Jr, A.W., 1991. Consideration of the chemistry of radon progeny. Environmental science & technology, 25(4), pp.730-735.
Hopke, P., 1996. The initial atmospheric behavior of radon decay products. Journal of Radioanalytical and Nuclear Chemistry, 203(2), pp.353-375.
mali73 t1_jch9lo4 wrote
Yes, you're right with compelling literature. I should've looked into the actual conditions the daughter joins are formed under but I typed it at 1am. I get rilled up if I see poor reasoning and tend to go after it without consideration of context and probably should've stopped after the first paragraph.
KbarKbar t1_jcahmz4 wrote
To add to the already-excellent analysis already posted, I have to quibble about:
>There’d be a gradient originating from the source...
Exactly what "source" are you envisioning here? We're talking about radon gas mixed freely in the atmosphere. Any decay products would be distributed randomly and diffusely, as there is no monolithic source from which to originate.
Bbrhuft t1_jcffirz wrote
He was correct. Lead oxide isn't formed.
There's several factors that need to be considered. The fact that the Lead-214 daughter is singly ionized so reactions with oxygen aren't favoured, that air is humid and is often contaminated with VOCs and SO2, especially indoor air, and the fact that these reactions take place within an ionization trail generated by the Alpha particle, that generates hydroxy radicals from atmospheric humidity and NO2 (the radon daughter atoms recoil at 10-13 million mph btw).
Instead, Lead-214 will most often form tiny clusters surrounded by 5 to 8 water molecules and likely often a few molecules of VOCs. They measured the size of the clusters, they average 1.2 - 2 nm in diameter. Po-218 is a little different, it forms larger 15 nm clusters additionally with SO2 (once air contains a few ppm of SO2) and as, well as much smaller clusters of PoOx 0.5 - 1 nm in diameter (the proportion of these clusters depends on what's in the air).
Castleman Jr, A.W., 1991. Consideration of the chemistry of radon progeny. Environmental science & technology, 25(4), pp.730-735.
Hopke, P., 1996. The initial atmospheric behavior of radon decay products. Journal of Radioanalytical and Nuclear Chemistry, 203(2), pp.353-375.
Lazz45 t1_jcfim9y wrote
I would take source to be the largest point of entry, and point from where the radon gas diffuses out into say the basement. However, I see your point in that it's not like a heat source or lead atom generator that constantly acts like a "lead source"
From what I can see, the gas gets in via cracks/voids in the foundation so in theory you could take those points of entry as "sources"
7eggert t1_jcafavh wrote
If you regard "finding the lead atom" I might agree, but "ionized(?) lead atom finds oxygen in air" would be one in five collisions.
NeverPlayF6 t1_jcb2y0g wrote
There is no way that it is more likely to find other lead atoms, which are only there at trace amounts as decay products, before it interacts with trillions upon trillions of other gas molecules... many of which are reactive.
[deleted] t1_jc9zjyb wrote
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